Chemistry Paper -II Bihar B.Sc Fifth Semester book

Unit

Topics

Hours

1

Polynuclear Hydrocarbons:

Nomenclature of polynuclear hydrocarbons, preparation and properties and constitution of naphthalene, anthracene and phenanthrene.

cgqukfHkdh; gkbMªksdkcZu&

cgqukfHkdh; gkbMªksdkcZu dk ukedj.k] us¶+Fkyhu] ,UFkzslhu vkSj QsusaFkzhu dh rS;kjh vkSj xq.k vkSj lajpukA

12

2

Nitrogen containing Compounds: Amines, Nitriles, Isocyanides and Diazonium Compound:

Reduction of nitro compounds under different conditions, von Richter reaction, preparation and separation of primary, secondary and tertiary amines, relative basic strength of amines, distinctions among primary, secondary and tertiary amines, preparation of diazonium salts and their synthetic applications, diazo coupling reactions, Gomberg reaction, preparation and properties of nitriles and isonitriles.

ukbVªkstu ;qDr ;kSfxd& ,sehu] ukbVªkby] vkblkslk;ukbM vkSj Mkb,t+ksfu;e ;kSfxd&

fofHkUu fLFkfr;ksa ds vUrxZr ukbVªks ;kSfxdksa dk vip;u] o‚u fjDVj vfHkfØ;k] çkFkfed] f}rh;d vkSj r`rh;d ,sehu dh rS;kjh vkSj i`FkDdj.k] ,sehu dh lkisf{kd {kkjh; lkEkF;Z] çkFkfed] f}rh;d vkSj r`rh;d ,sehu ds chp Hksn] Mkb,t+ksfu;e yo.k dh rS;kjh vkSj muds flaFksfVd vuqç;ksx] Mkb,t+ks ;qXeu vfHkfØ;k] xksEcxZ vfHkfØ;k] ukbVªkby vkSj vkblksukbVªkby dh rS;kjh vkSj xq.kA

15

3

Heterocyclic Compounds:

Classification and nomenclature of heterocyclic compounds, aromaticity in 5 and 6-membered rings with one heteroatom, syntheses of pyrrole (Knorr-Pyrrole synthesis, Paal-Knorr synthesis, Hantzsch synthesis), Reaction synthesis and constitutions of furan, thiophene, pyridine (Hantzsch synthesis), reactions of pyrrole, furan, thiophene and pyridine.

Quinoline and isoquinoline: 

Reactions, syntheses and constitution of quinoline and isoquinoline. (Skraup synthesis, Friedlander’s Synthesis, Knorr
Quinoline Synthesis, Bischler Napieralski Synthesis)

fo"kepØh; ;kSfxd&

fo"kepØh; ;kSfxdksa dk oxÊdj.k vkSj ukedj.k] ,d fo"keijek.kq ds lkFk 5 vkSj 6&lnL;h; oy; esa ,sjksesfVdrk] ikbjksy ds la'ys"k.k ¼uksj&ikbjksy la'ys"k.k] ikWy&uksj la'ys"k.k] gaV~t+ la'ys"k.k½] ¶;wjku] fFk;ksQhu] ikbjhMhu ¼gaV~t+ la'ys"k.k½ dh vfHkfØ;k la'ys"k.k vkSj fuekZ.k] ikbjksy] ¶;wjku] fFk;ksQhu vkSj ikbjhMhu dh vfHkfØ;k,¡A

fDouksfyu vkSj vkblksfDouksfyu&

fDouksfyu vkSj vkblksfDouksfyu dh vfHkfØ;k,¡] la'ys"k.k vkSj fuekZ.kA ¼LØ‚i la'ys"k.k] ÝkbMySaMj dk la'ys"k.k] u‚j fDouksfyu la'ys"k.k] fc'yj usfi;jYLdh la'ys"k.k½

12

4

Alkaloids and Terpenoids:

Natural occurrence, classification and isolation of alkaloids and terpenoids, isoprene. Isoprene and Special Isoprene rule, reactions used in general methods involved in structural elucidation of alkaloids and terpenoids.

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,sYdsy‚bM vkSj VsjisuksbM~l dh çk—frd ÁkfIr LFkku] oxÊdj.k vkSj i`FkDdj.k] vkblksçhuA vkblksçhu vkSj fo'ks"k vkblksçhu fu;e] ,sYdsy‚bM vkSj VsjisuksbM~l dh lajpukRed O;k[;k esa 'kkfey lkekU; fofèk;ksa esa ç;qDr vfHkfØ;k,¡A

09

Total ¼dqy½

48