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All Home --MBA ---Uttar Pradesh | MBA | ----D.El.Ed. Books Online -----Haryana D.El.Ed Books ------D.EL.ED 1st Year Books (Haryana) ------D.EL.ED 2nd Year Books (Haryana) -----Uttar Pradesh D.El.Ed Books ------1st Sem U.P D.EL.ED(BTC) Books ------2nd Sem U.P D.EL.ED (BTC) Books ------3rd Semester U.P D.EL.ED(BTC) Books ------4th Sem U.P D.EL.ED (BTC) books -----Madhya Pradesh D.El.Ed Books ------D.EL.ED 1st Year Books ( Madhay Pradesh) ------D.EL.ED 2nd Year Books (Madhay Pradesh) -----Bihar D.El.Ed Books ------D.EL.ED 1st Year Books ------D.EL.ED 2nd Year Books -----Jharkhand D.El.Ed Books ------D.EL.ED 1st Year Books JAC ------D.EL.ED 2nd Year Books ----Dr. A.P.J. Abdul Kalam Technical University | AKTU | -----First Sem | MBA | AKTU -----Second Sem | MBA | AKTU -----Third Sem | MBA | AKTU -----Fourth Sem | MBA | AKTU ---Madhya Pradesh | MBA | ----Barkatullah University | MBA | -----First Sem | MBA | Barkatullah University -----Second Sem | MBA | Barkatullah University -----Third Sem | MBA | Barkatullah University -----Fourth Sem | MBA | Barkatullah University ---Haryana ----Maharshi Dayanand University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----Kurukshetra University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Karnataka ----Bangalore University -----First sem -----Second sem -----Third sem -----Fourth sem ----Visvesvaraya Technological University -----First sem -----Second sem -----Third sem -----Fourth sem ----Bengaluru City University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----Bengaluru North University (BNU ) -----First Sem -----Second Sem ---Tamil Nadu ----Anna University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----Bharathiar University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Maharashtra ----University of Pune -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----Nagpur University (RTMNU) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----Dr. Babasaheb Ambedkar Marathwada University (BAMU) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----Shivaji University, Kolhapur (SUK) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Andhra Pradesh ----JNTU Anantapur -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----JNTU Kakinada -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ----Andhra University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Kerala ----A P J Abdul Kalam Technological University (KTU) -----First Semester -----Second Semester -----Third Semester -----Fourth Semester ---Punjab ----I.K.Gujral Punjab Technical University (PTU) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Rajasthan ----Rajasthan Technical University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Odisha ----Biju Patnaik University of Technology -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---West Bengal ----Maulana Abul Kalam Azad University of Technology (WBUT) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Third Sem ---Gujarat ----Gujarat Technological University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Uttarakhand ----Uttarakhand Technical University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem ---Delhi ----Guru Gobind Singh Indraprastha University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem --BBA ---Uttar Pradesh ----University of Lucknow -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Dr. Bhimrao Ambedkar University, Agra -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----BBA Books of UP State Universities -----First Semester -----Second Semester -----Third Semester -----Fourth Semester -----Fifth Semester -----Sixth Semester ----Chaudhary Charan Singh University, Meerut/Maa Shakambhari University, Saharanpur -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Semester -----Sixth Semester ----Dr. A.P.J. Abdul Kalam Technical University | AKTU | -----First Sem -----Second Sem ---Delhi ----Guru Gobind Singh Indraprastha University -----first Semester -----second semester -----Third Semester -----Fourth Sem -----Fifth Sem -----Sixth Sem ---Madhya Pradesh ----Madhya Pradesh (Department Of Higher Education) -----First Year ------English ------Bilingual -----Second Year ------English ------Bilingual ---Haryana ----Kurukshetra University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Maharshi Dayanand University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ---Karnataka ----Rani Channamma University Belagavi -----First Sem -----Second Sem -----Third Sem -----Fouth Sem -----Fifth Sem -----Sixth Sem ----Karnatak University, Dharwad -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Bangalore University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Karnataka State HEC (NEP2020 Syllabus) -----First Semester -----Second Semester -----Third Semester -----Fourth Semester -----Fifth Sem -----Sixth Sem ----Bengaluru City University -----First Semester -----Second Semester ---Tamil Nadu ----Bharathiar University -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----University of Madras -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ---Maharashtra ----Savitribai Phule Pune University (SPPU) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Rashtrasant Tukadoji Maharaj Nagpur University (RTMNU) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ---Andhra Pradesh ---Punjab ----Punjab Technical University (PTU) -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Punjabi University, Patiala -----First Sem -----Second Sem -----Third Sem ---Rajasthan ----University of Rajasthan -----Part- I -----Part- II -----Part- III -----Fourth Sem -----Fifth Semester -----Sixth Semester ---U.P. State Universities (NEP 2020 common minimum syllabus) ----U.P. State University -----First Sem -----Second Sem -----Third Semester -----Fourth Semester -----Fifth Semester -----Sixth Semester ----Veer Bahadur Singh Purvanchal University, Jaunpur -----First Sem -----Second Sem -----Kunji ------First Sem ------Second Sem ----Chaudhary Charan Singh University, Meerut -----First Sem ------English ------Hindi ----Dr. Bhimrao Ambedkar University, Agra -----First Sem -----Second Sem ----Chhatrapati Shahu Ji Maharaj University, Kanpur -----First Sem -----Second Sem ----Mahatma Jyotiba Phule Rohilkhand University, Bareilly -----First Sem -----Second Sem ----Mahatma Gandhi Kashi Vidyapith, Varanasi -----First Sem -----Second Sem ----Dr. Ram Manohar Lohia Avadh University, Ayodhya -----First Sem -----Second Sem ----Deen Dayal Upadhyaya Gorakhpur University -----First Sem -----Second Sem ----Prof. Rajendra Singh (Rajju Bhaiya) University, Prayagraj -----First Sem -----Second Sem ---Uttrakhand State Universities (NEP 2020 common minimum syllabus) ----BBA -----First semester ---UOR (Jaipur) NEP-2020 ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ---Haryana (NEP-2020) ----First Sem ----Second Sem ---West Bengal ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ---BBA (CA),B.Com (CA) ----Pune -----First Sem -----Second Sem -----Third Sem --BCA ---UP State Universities ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ----Fifth Sem ----Sixth Sem ---University of Pune ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ----Fifth Sem ----Sixth Sem ---I.K.Gujral Punjab Technical University (PTU) ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ----Fifth Sem ----Sixth Sem ----Other ---University of Rajasthan ----Part I ----Part II ----Part III ---Rashtrasant Tukadoji Maharaj Nagpur University ----EVEN SEMESTER ----ODD SEMESTER ---Uttar Pradesh NEP2020 ----Chhatrapati Shahu Ji Maharaj University, Kanpur -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Chaudhary Charan Singh University, Meerut -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----University of Lucknow -----First Sem -----Second Sem -----Third Sem -----Fourth Sem -----Fifth Sem -----Sixth Sem ----Mahatma Gandhi Kashi Vidyapith ----PRSU ,Prof. Rajendra Singh (Rajju Bhaiya) University, Prayagraj NEP2020 -----First Sem ---University of Rajasthan ,Jaipur (According to NEP-2020) ----First Sem ----Second Sem ----Third Sem ---BCCA (B. 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Com ---Bangalore University ---Haryana NEP-2020 ( Kuk ) ----First Sem -----English -----Bilingual ----Second Sem -----English -----Bilingual ----Third Sem -----English -----Bilingual ---Rashtrasant Tukadoji Maharaj Nagpur University ----First Sem ----Second Sem ----Third Semester ----Fourth Semester ----Fifth Sem ----Six Sem ---I.K.Gujral Punjab Technical University (PTU) ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ----Fifth Sem ----Sixth Sem ---University of Madras ----First Sem ----Second Sem ----Third Semester ----Fourth Semester ----Fifth Semester ----Sixth Sem ---University of Lucknow ----First Sem -----English -----Hindi -----Bilingual ----Second Sem -----English -----Hindi -----Bilingual ----Third Sem -----Hindi -----English -----Bilingual ----Fourth Sem -----English -----Bilingual ----Fifth Sem -----English -----Bilingual ----Sixth Sem -----English -----Bilingual ---University of Pune ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ----Fifth Sem ----Sixth Sem ---U.P. State Universities ----B.Com 1st semester Books -----English Edition B.com 1st Sem -----Bilingual Edition B.Com 1st Sem ----B.Com 2nd Sem Books in Hindi and English -----B.com 2nd sem English books for UP State universities -----B.Com 2nd Sem Hindi Books (Bilingual) for UP State Universities -----Hindi ----B.Com 3rd Sem Books for UP State Universities -----Bilingual Format B.Com 3rd Sem -----B.Com 3rd sem English Books for UP State Universities ----B.com 4th Sem Books In Hindi & English UP State -----B.com 4th sem English Books of UP State Universities -----Bilingual Edition B.Com 4th Sem ----B.com 5th Sem Books In Hindi & English UP State -----English -----Bilingual ----B.com 6th Sem Books In Hindi & English UP State -----English -----Bilingual ----Veer Bahadur Singh Purvanchal University, Jaunpur -----First Sem ------English ------Hindi ----Chaudhary Charan Singh University, Meerut -----First Sem ------English ------Hindi ----Chhatrapati Shahu Ji Maharaj University, Kanpur -----First Sem -----Second Sem ----Dr. Bhimrao Ambedkar University, Agra -----First Sem -----Second Sem ----Mahatma Gandhi Kashi Vidyapith, Varanasi -----First Sem -----Second Sem ----Deen Dayal Upadhyaya Gorakhpur University -----First Sem -----Second Sem ----Prof. Rajendra Singh (Rajju Bhaiya) University, Prayagraj -----First Sem -----Second Sem ----Dr. Ram Manohar Lohia Avadh University, Ayodhya -----First Sem -----Second Sem ----Mahatma Jyotiba Phule Rohilkhand University, Bareilly -----First Sem -----Second Sem ---Madhya Pradesh ----Madhya Pradesh (Department Of Higher Education) -----First Year ------English ------Bilingual -----Second Year ------English ------Bilingual ---Uttarakhand ----Uttarakhand State Universities -----First Sem -----Second Sem -----Third Sem ---BIHAR ----First Sem -----ENGLISH -----Bilingual ----Second Sem -----English -----Bilingual ----Third Sem -----English -----Bilingual ----Fourth Sem ----Fifth Sem ----Sixth Sem ---University of Rajasthan (Jaipur) NEP ----First Sem -----English -----Bilingual ----Second Sem -----English -----Bilingual ----Third Sem -----English -----Bilingual ----Fourth Sem -----English -----Bilingual --M. Sc (IT) ---I.K.Gujral Punjab Technical University (PTU) ----First Sem ----Second Sem ----Third Sem ----Fourth Sem --B. Sc (IT) ---I.K.Gujral Punjab Technical University (PTU) ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ----Fifth Sem ----Sixth Sem --B.Tech ---A P J Abdul Kalam Technological University (KTU) ----First Sem ----Second Sem ----Third Sem ----Fourth Sem ----Fifth Sem ----Sixth Sem ----Seventh Sem ----Eight Sem ---Aryabhatta Knowledge University (AKU) ----First Semester ----Second Semester ----Third Semester ----Fourth Semester --B.A ---B.A. Of U.P. 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U.P. State Universities Common Syllabus NEP ----B.Sc First Sem Books | U.P. State Universities -----ENGLISH EDITION | B.Sc 1st Sem Books -----BILINGUAL EDITION | B.Sc 1st Sem Books ----B.Sc Second Sem Books | U.P. States Universities -----English Edition | U.P. B.Sc 2nd Sem -----Bilingual Edition | U.P. B.Sc 2nd Sem Book ----B.Sc Third Sem Books | UP State Universities -----B.Sc 3rd sem English Books -----B.Sc 3rd Sem Hindi Books (Bilingual- Hindi + English) ----B.Sc Fourth Sem Books | UP State Universities -----B.Sc 4th sem English Books -----B.Sc 4th Sem HIndi Books(Bilingual- HIndi+English) ----B.Sc Fifth Sem Books | U.P. State Universities -----English -----Bilingual ----B.Sc Sixth Sem Books | U.P. State Universities -----English -----Bilingual ---Veer Bahadur Singh Purvanchal University, Jaunpur ----First Sem -----English -----Hindi ----Second Sem ---University of Lucknow ----First Sem -----Bilingual ----Second Sem -----Bilingual -----English ----Third Sem -----English -----Bilingual ---Chaudhary Charan Singh University, Meerut ----First Sem ---Madhya Pradesh ----Madhya Pradesh (NEP2020 Department Of Higher Education) -----First Year ------English ------Bilingual -----Second Year ---Chhatrapati Shahu Ji Maharaj University, Kanpur ----First Sem ----Second Sem ---Dr. Bhimrao Ambedkar University, Agra ----First Sem ----Second Sem ---Mahatma Gandhi Kashi Vidyapith, Varanasi ----First Sem ----Second Sem ---DEEN DAYAL UPADHYAYA GORAKHPUR UNIVERSITY ----First Sem ---Prof. Rajendra Singh (Rajju Bhaiya) University, Prayagraj ----First Sem ---Dr. Ram Manohar Lohia Avadh University, Ayodhya ----First Sem ----Second Sem ---Mahatma Jyotiba Phule Rohilkhand University, Bareilly ----First Sem ----Second Sem ---Uttarakhand State Universities ----First Semester -----Bilingual ----Second Semester ---B.Sc. 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-----Second Year ----Pandit Deendayal Upadhyaya Shekhawati University , ( Sikar Rajasthan ) -----First Sem ------Hindi ---Bihar ----Patliputra University -----First Year -----Second Year ----Magadh University -----First Year -----Second Year ----Babasaheb Bhimrao Ambedkar Bihar University -----First year -----Second year ---Chhattisgarh ----Pt Ravishankar Shukla University, Raipur -----First Sem -----Second Sem ---Rajasthan (B.A/B.Sc/B.ED) ----Rajasthan University -----First Year ------Hindi -----Second Year ------Hindi --Pharmacy ---B.Pharm Books ----B.PHARM 1st SEM ----B.PHARM 2nd SEM ----B.PHARM 3rd SEM ----B.PHARM 4th SEM ----B.PHARM 5th SEM ----B.PHARM 6th SEM ----B.PHARM 7th SEM ----B.PHARM 8th SEM ---D.Pharm Books ----D.Pharm 1st Year Books -----D.Pharm Books in English -----D.Pharm Bilingual Books ----D.Pharm 2nd Year Books -----D.Pharm Books in English -----D.Pharm Books in Bilingual ----D.Pharma Exit Examination Kit ---DHP ----First year ----Second Year ---Joy Publication ----D Pharma -----First Year ------English ------Bilingual -----Second Year ------English ------Bilingual --Nursing ---ANM Books ----First year ----Second year ----First year -----Hindi -----English -----Bilingual ----Second Year -----Hindi -----English -----Bilingual ---B.Sc. Nursing Books ----B.Sc. Nursing 1st Sem ----B.Sc Nursing 2nd Sem ----B.Sc Nursing 3rd Sem ----B.sc Nursing 4th Sem ----B.Sc. Nursing 5th Sem ----Sixth Sem ----Seventh Sem ----Eight Sem ----B.Sc. Nursing 6th Sem ----B.Sc. Nursing 7th Sem ---G.N.M. [General Nursing and Midwifery] ----GNM 1st Year Books -----GNM Books in English -----GNM Books in Bilingual Format ([हिंदी-English]) ----GNM 2nd Year Books -----GNM Books in English -----GNM Books in Bilingual Format (हिंदी-English) ----GNM 3rd Year Books -----GNM Books in English -----GNM Books in Bilingual Format (हिंदी-English) --SWA Education ---(FSSAI) Food Safety and Standards Authority of India --MCA ---Jawaharlal Nehru Technological University, Kakinada ( JNTU-K ) ----First Sem ----Second Sem ----Third Sem ---Dr. A. P. J. Abdul Kalam Technical University, Lucknow ( AKTU ) ----First Sem ----Second Sem --TRADING --LL.B ---5 Year course All Semester ----First Sem ----Second Sem ----Third Sem ---3 Year Course All Semester ----First Sem ----Second Sem ----Third Sem
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  5. Chemistry (Paper-I) Organic Synthesis-A ( कार्बनिक संश्लेषण-A ) B.Sc 5th Semester U.P State

Chemistry (Paper-I) Organic Synthesis-A ( कार्बनिक संश्लेषण-A ) B.Sc 5th Semester U.P State

Organic Synthesis-A Book B.Sc 5th Semester U.P
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Organic Synthesis-A Book B.Sc 5th Semester U.P
Organic Synthesis-A Book B.Sc 5th Semester U.P

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AUTHORS : Dr. Rajesh Chandra Verma , Dr. Vijay Deep Sharma , Dr. Sanjeev Kumar Mishra , Dr. Moh. Irfan Ahmad Khan , Dr. Rashmi Gupta 

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 Syllabus

 

 

Organic Synthesis-A ¼dkcZfud la’ys"k.k&A½

 

Course Code: B020501T

 

 

Unit

Topics

No. of Lectures

I

Chemistry of Alkanes and Cycloalkanes

A) Alkanes: Classification of carbon atom in alkanes, General methods of preparation, physical and chemical properties of alkanes: Wurtz Reaction, Wurtz-Fittig Reactions, Free radical substitutions:

Halogenation -relative reactivity and selectivity

 

B) Cycloalkanes: Nomenclature, methods of formation, chemical reactions, Baeyer's strain theory and its limitations. Chair, Boat and Twist boat forms of cyclohexane with energy diagrams ring strain in small rings, theory of strain less rings. The case of cyclopropane ring, banana bonds.

,sYdsUk vkSj lkbDyks,sYdsUk dk jlk;u

,sYdsUk& ,sYdsUk esa dkcZu ijek.kq dk oxhZdj.k] cukus dh lkekU; fof/k] ,sYdsUk ds HkkSfrd vkSj jklk;fud xq.k/keZ& oqVZ~t vfHkfØ;k] oqVZ~t&fQfVx vfHkfØ;k,a] eqDr ewyd çfrLFkkiu&

gSykstuhdj.k&lkis{k vfHkfØ;k'khyrk vkSj p;ukRedrk

 

lkbDyks,sYdsUk& ukedj.k] cukus dh fof/k;k¡] jklk;fud vfHkfØ;k,a] cs;j dk foÑfr fl)kar vkSj bldh lhek,aA ÅtkZ vkjs[kksa ds lkFk lkbDyksgsDlsu ds dqlhZ] uko vkSj fV~oLV uko :i] NksVs oy;ksa esa oy; ruko] foÑfr oy; dk fl)karA lkbDyksçksisu oy;] dsyk ca/k dh fLFkfrA

8

II

 

Chemistry of Alkenes

Methods of formation of alkenes, Addition to C=C: mechanism (with evidence wherever applicable), reactivity, regioselectivity (Markownikoff and anti-Markownikoff additions) and stereoselectivity; reactions: hydrogenation, halogenation, hydrohalogenation, hydration, oxymercuration demercuration, hydroboration-oxidation, epoxidation, syn and anti-hydroxylation, ozonolysis, addition of singlet and triplet carbenes; Simmons-Smith cyclopropanation reaction; electrophilic addition to diene (conjugated dienes and allene); radical addition: HBr addition; mechanism of allylic and benzylic bromination in competition with brominations across C=C; use of NBS; interconversion of E- and Z- alkenes.

 

,sYdhu dk jlk;u

,sYdhu ds fuekZ.k dh fof/k;k¡] C=C esa TkqM+uk& fØ;kfof/k ¼tgk¡ Hkh ykxw gks lk{; ds lkFk½] vfHkfØ;k'khyrk] jhft;kslsysfDVfoVh ¼ekdksZfud‚Q vkSj ,aVh&ekdksZfud‚Q ;ksx½ vkSj LVhfj;kslsysfDVfoVh; vfHkfØ;k,¡& gkbMªkstuhdj.k] gSykstuhdj.k] gkbMªksgSykstuhdj.k] ty;kstu] v‚DlheD;wZjs'ku MheD;wZjs'ku] gkbMªkscksjs'ku&v‚Dlhdj.k] ,i‚Dlhdj.k] flu vkSj ,aVh&gkbMª‚fDlys'ku] vkstksuksfyfll] flaXysV vkSj fVªIysV dkchZu dk tksM+; lheu&fLeFk lkbDyksçksisus'ku vfHkfØ;k; MkbbZu esa bysDVªkWLusgh tksM+ ¼la;qfXer MkbbZu vkSj ,sYkhu½; ewyd tksM+& HBr tksM+; C=C esa czksfeuhdj.k ds lkFk çfrLi/kkZ esa ,sfyfyd vkSj csatkbfyd czksfeuhdj.k dh fØ;kfof/k NBS dk mi;ksx+; E- vkSj Z-,sYdhu dk varjk:ikarj.kA

12

III

 

Chemistry of Alkynes

Methods of formation of alkynes, Addition to C≡C, mechanism, reactivity, regioselectivity and  stereoselectivity reactions: hydrogenation, halogenations, hydrohalogenation, hydration, oxymercuration demercuration, hydroboration-oxidation, dissolving metal reduction of alkynes (Birch); reactions of terminal alkynes by exploring its acidity; inter conversion of terminal and nonterminal alkynes.

 

,sYdkbUk dk jlk;u

,sYdkbuksa ds fuekZ.k dh fof/k;k¡] C≡C esa ;ksx] fØ;kfof/k] vfHkfØ;k'khyrk] jsft;kslsysfDVfoVh vkSj f=foe p;ukRedrk; vfHkfØ;k,¡& gkbMªkstuhdj.k] gSykstuhdj.k] gkbMªksgSykstuhdj.k] ty;kstu] v‚DlheD;Zwjs'ku MheD;Zwjs'ku] gkbMªkscksjs'ku&v‚Dlhdj.k] ,sYdkbUk ¼cpZ½ dh /kkrq esa foys; vip;u+; bldh vEyrk dh [kkst djds VfeZuy ,sYdkbUk dh vfHkfØ;k,a+; VfeZuy vkSj u‚u&VfeZuy ,sYdkbuksa dk varjk:ikarj.kA

06

IV

Aromaticity and Chemistry of Arenes

Nomenclature of benzene derivatives, MO picture of benzene, Aromaticity: Hückel’s rule, aromatic character of arenes, cyclic carbocations/carbanions. Electrophilic aromatic substitution: halogenation, nitration, sulphonation and Friedel-Crafts alkylation/acylation with their Mechanism. Directing effects of the groups. Birch reduction, Methods of formation and chemical reactions of alkylbenzenes, alkynylbenzenes and biphenyl, naphthalene and anthracene.

 

 

,sjhu dh ,sjkseSfVdrk vkSj jlk;u

csathu O;qRiUu dk ukedj.k] csathu dk MO fp=] ,sjkseSfVdrk& gdy dk fu;e] ,sjhu dk ,sjkseSfVd xq.k] pØh; dkcZ/kuk;u/dkcZ_.kk;uA bysDVªkuLusgh ,jkseSfVd çfrLFkkiu& gSykstuhdj.k] ukbVªhdj.k] lYQksuhdj.k vkSj ÝhMsy&Øk¶V~l ,fYdys'ku/,lkbys'ku muds fØ;kfof/k ds lkFkA lewgksa dk funsZ'ku çHkko- cpZ vip;u] ,sfYdycsUthu] ,sYdkbfuycasthu vkSj ckbQsfuy] uS¶Fkyhu vkSj ,UFkzklhu ds fuekZ.k vkSj jklk;fud vfHkfØ;kvksa dh fof/k;k¡A

10

V

 

Chemistry of Alcohols

Classification and nomenclature, Monohydric alcohols – nomenclature, methods of formation by reduction of Aldehydes, Ketones, Carboxylic acids and Esters, Hydrogen bonding, Acidic nature, Reactions of alcohols.

 

Dihydric alcohols nomenclature, methods of formation, chemical reactions of vicinal glycols, oxidative cleavage [Pb(OAc)4 and HIO4] and pinacol pinacolone rearrangement. Trihydric alcohols - nomenclature, methods of formation, chemical reactions of glycerol.

 

,Ydksgy dk jlk;u

oxhZdj.k vkSj ukedj.k] eksuksgkbfMªd ,Ydksgy & ukedj.k] ,sfYMgkbM] dhVksUk] dkcksZfDlfyd vEy vkSj ,LVj ds vip;u ls cukus dh fof/k;ka] gkbMªkstu ca/k] vEyh; ç—fr] ,Ydksgy dh vfHkfØ;k,aA

 

MkbgkbfMªd ,Ydksgy ukedj.k] cukus dh fof/k;k¡] fofluy XykbdkWy dh jklk;fud vfHkfØ;k,a] v‚DlhMsfVo fonyu [Pb(OAc)4 vkSj HIO4] vkSj fiukdksy fiukdksyksu iquO;ZoLFkkiuA VªkbgkbfMªd ,Ydksgy & ukedj.k] fuekZ.k dh fof/k;k¡] fXylj‚y dh jklk;fud vfHkfØ;k,¡A

8

VI

 

Chemistry of Phenols: Nomenclature, structure and bonding, preparation of phenols, physical properties and acidic character, Comparative acidic strengths of alcohols and phenols, resonance stabilization of phenoxide ion. Reactions of phenols – electrophilic aromatic substitution, acylation and carboxylation. Mechanisms of Fries rearrangement, Claisen rearrangement, Gatterman syntheis, Hauben Hoesch reaction, Lederer-Manasse reaction and Reimer-Tiemann reaction

 

fQuksy dk jlk;u& ukedj.k] lajpuk vkSj ca/k] fQuksy dks cukuk] HkkSfrd xq.k/keZ vkSj vEyh; xq.k] ,Ydksgy vkSj fQuksy dh rqyukRed vEyh; izcyrk] fQukWDlkbM vk;u dk vuqukn fLFkjhdj.kA fQuksy dh vfHkfØ;k,a & bysDVªkWu Lusgh ,sjkseSfVd çfrLFkkiu] ,sflyhdj.k vkSj dkcksZfDlyhdj.kA Ýkbt iquO;ZoLFkkiu] Dyslsu iquO;ZoLFkkiu] xkVjeSu la’ys"k.k gkmcsu gks'k vfHkfØ;k] ysMjj&ekuls vfHkfØ;k vkSj jhej&Vheu vfHkfØ;k dh fØ;kfof/k

06

VII

 

Chemistry of Ethers and Epoxides: Nomenclature of ethers and methods of their formation, physical properties, Chemical reactions – cleavage and autoxidation, Ziesel's method. Synthesis of epoxides, Acid and base-catalyzed ring opening of epoxides, orientation of epoxide ring opening, reactions of Grignard and organolithium reagents with epoxides.

bZFkj vkSj ,i‚DlkbM dk jlk;u & bZFkj dk ukedj.k vkSj buds cukus dh fof/k;k¡] HkkSfrd xq.k/keZ] jklk;fud vfHkfØ;k,a & fonyu vkSj v‚Vksv‚DlhMs'ku] ftlsy dh fof/kA ,i‚DlkbM~l dk la'ys"k.k] ,i‚DlkbM~l dk vEy vkSj {kkj&mRçsfjr oy; dk [kqyuk] ,i‚DlkbM oy; [kqyuk dk vfHkfoU;kl] ,i‚DlkbM~l ds lkFk fxzXukMZ vkSj dkcZfyfFk;e vfHkdeZdksa dh vfHkfØ;k,aA

05

VIII

 

Chemistry of Organic Halides

Nomenclature and classes of alkyl halides, methods of formation, chemical reactions, Mechanisms of nucleophilic substitution reactions of alkyl halides, SN2 and SN1 reactions with energy profile diagrams; Polyhalogen compounds: Chloroform, carbon tetrachloride; Methods of formation of aryl halides, nuclear and side chain reactions; The addition-elimination and the elimination-addition mechanisms of nucleophilic aromatic substitution reactions; Relative reactivities of alkyl halides vs allyl, vinyl and aryl halides, Synthesis and uses of DDT and BHC.

 

dkcZfud gSykbM~l dk jlk;u

,sfYdy gSykbMksa dk ukedj.k vkSj oxZ] cukus dh fof/k;k¡] jklk;fud vfHkfØ;k,a] ,sfYdy gSykbMksa dh ukfHkdLusgh çfrLFkkiu vfHkfØ;kvksa dh fØ;kfof/k ÅtkZ çksQkby vkjs[kksa ds lkFk SN2 vkSj SN1 vfHkfØ;k,a; i‚yhgSykstu ;kSfxd& DyksjksQ‚eZ] dkcZu VsVªkDyksjkbM; ,sfjy gSykbM~l ds fuekZ.k dh fof/k;k¡] ijek.kq vkSj ik'oZ J`a[kyk vfHkfØ;k,¡; ukfHkdLusgh ,sjkseSfVd çfrLFkkiu vfHkfØ;kvksa ds vfrfjDr&foyksiu vkSj foyksiu &;ksx fØ;kfof/k; ,sfYdy gSykbM cuke ,sfyy] foukby vkSj ,sfjy gSykbM dh lkis{k vfHkØ;k,¡] DDT vkSj BHC dk la'ys"k.k vkSj mi;ksxA

05

 

U.P State NEP2023/B.SC ( Bilingual )/5/05
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